Serveur d'exploration sur le cobalt au Maghreb

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Cobalt spinel CoAl2O4 via sol-gel process: elaboration and surface properties

Identifieur interne : 000155 ( Maroc/Analysis ); précédent : 000154; suivant : 000156

Cobalt spinel CoAl2O4 via sol-gel process: elaboration and surface properties

Auteurs : S. Chemlal [Maroc] ; A. Larbot [France] ; M. Persin [France] ; J. Sarrazin [France] ; M. Sghyar [Maroc] ; M. Rafiq [Maroc]

Source :

RBID : ISTEX:003A81CF6BC6B3570858CF3D2175F99ACA36D531

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Abstract

In this work the preparation of cobalt spinel CoAl2O4 is described. The technique of colloidal solution destabilization was used as the sol-gel process. The powder obtained from the dried gel was characterized by thermal analysis (thermogravimetric and differential), X-ray diffraction, infrared spectroscopy, and specific surface area measurement. Crystallization of CoAl2O4 spinels occurs at about 400°C. The study of surface properties (surface charge and electrophoretic mobility) of the spinel powder fired at 600°C, in suspension in different electrolyte solutions (10−3 molar ionic strength), shows that the spinel material charge depends on the pH of the solution. The spinel sol was used for the preparation of membrane by the slip-casting method.

Url:
DOI: 10.1016/S0025-5408(00)00444-X


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ISTEX:003A81CF6BC6B3570858CF3D2175F99ACA36D531

Le document en format XML

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<term>A. Ceramics</term>
<term>A. Inorganic compounds</term>
<term>A. Oxides</term>
<term>Aluminium oxide</term>
<term>B. Sol-gel chemistry</term>
<term>Characterization</term>
<term>Cobalt oxide</term>
<term>Colloidal suspension</term>
<term>Crystallization</term>
<term>D. Surface properties</term>
<term>Destatization</term>
<term>Electrophoretic mobility</term>
<term>Experimental study</term>
<term>Heat treatment</term>
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<term>Sol gel process</term>
<term>Spinels</term>
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<term>8110D</term>
<term>8270</term>
<term>Aire superficielle</term>
<term>Al Co O</term>
<term>Aluminium oxyde</term>
<term>Caractérisation</term>
<term>Charge superficielle</term>
<term>CoAl2O4</term>
<term>Cobalt oxyde</term>
<term>Coulée en barbotine</term>
<term>Cristallisation</term>
<term>Déstatisation</term>
<term>Etude expérimentale</term>
<term>Membrane</term>
<term>Mobilité électrophorétique</term>
<term>Morphologie</term>
<term>Poudre</term>
<term>Procédé sol gel</term>
<term>Propriété thermique</term>
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<div type="abstract" xml:lang="en">In this work the preparation of cobalt spinel CoAl2O4 is described. The technique of colloidal solution destabilization was used as the sol-gel process. The powder obtained from the dried gel was characterized by thermal analysis (thermogravimetric and differential), X-ray diffraction, infrared spectroscopy, and specific surface area measurement. Crystallization of CoAl2O4 spinels occurs at about 400°C. The study of surface properties (surface charge and electrophoretic mobility) of the spinel powder fired at 600°C, in suspension in different electrolyte solutions (10−3 molar ionic strength), shows that the spinel material charge depends on the pH of the solution. The spinel sol was used for the preparation of membrane by the slip-casting method.</div>
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